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Beilstein J. Org. Chem. 2020, 16, 2551–2561, doi:10.3762/bjoc.16.207
Graphical Abstract
Figure 1: Selected TBTQ derivatives 1–5 that bind fullerenes in host–guest complexes.
Scheme 1: Synthetic route to TBTQ-(OG)6.
Figure 2: Fluorescence spectra of TBTQ-(OG)6 (5.0 × 10−6 M) with varying concentrations of (a) C60 and (b) C70...
Figure 3: Absorption spectra of (a) TBTQ-(OG)6 C60 [TBTQ-(OG)6: 50 μM; C60: 50 μM] and (b) TBTQ-(OG)6 C70 [...
Figure 4: Absorption spectra of (a) TBTQ-(OG)6 C60 [TBTQ-(OG)6: 50 μM; C60: 50 μM] and (b) TBTQ-(OG)6 C70 [...
Figure 5: Raman spectra of TBTQ-G6, C60 and TBTQ-G6 C60. Sample solutions of TBTQ-(OG)6 (50 μM) and TBTQ-(OG)...
Figure 6: Molecular model of the complex TBTQ-(OG)6 C60 in water, as generated by DFT calculations. (a) Side...
Figure 7: SEM images of (a) C60; (b) TBTQ-(OG)6; (c) and (d) TBTQ-(OG)6 C60 (C60: 1.4 mM; TBTQ-(OG)6: 1.4 mM...